Issue 88, 2024
From the journal:

Chemical Communications

Cationic dinuclear complexes [M2(PCP)2μ-Cl][GaCl4] of the group 10 elements. metallophilic interactions and catalytic dehydrogenation of Me2NHBH3†

Fabio Meyer,a   Pim Puylaert, ORCID logo a   Daniel Duvinage, ORCID logo a   Emanuel Hupf ORCID logo *a  and  Jens Beckmann ORCID logo *a  

* Corresponding authors

a Institute für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Str. 7, 28359 Bremen, Germany
E-mail: hupf@uni-bremen.de, j.beckmann@uni-bremen.de

Abstract

The facile synthesis of the cationic dinuclear group 10 complexes [M2(PCP)2μ-Cl]+ (M = Ni, Pd, Pt) by transmetallation from a simple Ga precursor is reported (PCP = 2,6-(Ph2P)C6H3). Their use for the catalysed dehydrogenation of Me2NHBH3 shows that Ni has a higher reactivity than Pt, whereas Pd is inactive.

Graphical abstract: Cationic dinuclear complexes [M2(PCP)2μ-Cl][GaCl4] of the group 10 elements. metallophilic interactions and catalytic dehydrogenation of Me2NHBH3

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Article information

DOI
https://doi.org/10.1039/D4CC04296D
Article type
Communication
Submitted
22 Aug 2024
Accepted
07 Oct 2024
First published
09 Oct 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 12912-12915

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Cationic dinuclear complexes [M2(PCP)2μ-Cl][GaCl4] of the group 10 elements. metallophilic interactions and catalytic dehydrogenation of Me2NHBH3

F. Meyer, P. Puylaert, D. Duvinage, E. Hupf and J. Beckmann, Chem. Commun., 2024, 60, 12912 DOI: 10.1039/D4CC04296D

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