Issue 89, 2024

Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane

Abstract

The reversible insertion of carbon dioxide into the silicon–nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO2 can be stored for extended periods and is only released upon heating to 133 °C.

Graphical abstract: Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane

Supplementary files

Article information

Article type
Communication
Submitted
16 Sep 2024
Accepted
10 Oct 2024
First published
17 Oct 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 13051-13054

Reversible CO2 insertion into the silicon–nitrogen σ-bond of an N-heterocyclic iminosilane

J. Wang, G. B. Hwang, C. E. Knapp and D. W. N. Wilson, Chem. Commun., 2024, 60, 13051 DOI: 10.1039/D4CC04798B

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