Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

Abstract

Peripherally unsubstituted dioxadiaza[8]circulene, as the first example of structurally identified pristine hetero[8]circulene, was synthesized by the substituent detachment reactions. The solid-state structures and photophysical properties were analysed to elucidate intermolecular interactions. Herzberg–Teller type emission was considered to explain the optical behavior.