On the nature of sub-THz continuum absorption in CO2 gas, its mixture with Ar, and in pure water vapor

Abstract

Detailed analysis of the unique broadband millimeter-wave (70–360 GHz) collision-induced absorption spectra in pure CO₂ and in its mixture with Ar is presented. The nature of the observed continuum absorption is examined using classical trajectory simulation along with statistical physics consideration. Bimolecular continuum is decomposed in the phase space into separate contributions from the so-called free, quasibound, and true bound molecular pairs, the proportions of which greatly vary with temperature. This partitioning is supported by consideration of the second virial coefficient and excluded volume in pure CO₂, Ar, and CO₂–Ar. Close similarity between collision-induced absorption in the CO₂ containing gases and the water vapor continuum in the subterahertz spectral range is demonstrated. This similarity suggests that the physical principles underlying both continuum absorption phenomena have much in common and, therefore, can be used for continuum modeling.