Issue 5, 2024
From the journal:

Dalton Transactions

Selective monooxygenation of diphosphenes with molecular oxygen†

Yuria Kawase,a   Shota Tsujimoto,a   Tomohiro Obayashi,a   Satoshi Kimura,a   Kanta Ito,a   Shotaro Ikoma,a   Kei Ota, ORCID logo a   Daisuke Hashizume ORCID logo b  and  Tsukasa Matsuo ORCID logo *a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
E-mail: t-matsuo@apch.kindai.ac.jp

b RIKEN Center for Emergent Matter Science (CEMS), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Abstract

The O2 splitting mediated by the bulky Rind-based diphosphenes resulted in the clean formation of the mixed-valent diphosphorus compounds, diphosphene oxides, with P2O moieties. Their structural features and electronic properties have been clearly characterized by experimental and theoretical methods.

Graphical abstract: Selective monooxygenation of diphosphenes with molecular oxygen

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Article information

DOI
https://doi.org/10.1039/D3DT04348G
Article type
Communication
Submitted
27 Dec 2023
Accepted
12 Jan 2024
First published
15 Jan 2024

Dalton Trans., 2024,53, 1956-1960

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Selective monooxygenation of diphosphenes with molecular oxygen

Y. Kawase, S. Tsujimoto, T. Obayashi, S. Kimura, K. Ito, S. Ikoma, K. Ota, D. Hashizume and T. Matsuo, Dalton Trans., 2024, 53, 1956 DOI: 10.1039/D3DT04348G

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