Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1−x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

Lei Liu; Chun-Yang Pan; Yong He; Li-Juan Zhong; Michael A. Beckett

doi:10.1039/D4DT00117F

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Co^(II)-doped hybrid Zn^(II) tetraborate complexes, [Zn_xCo_(1−x)(1,3-dap)B₄O₇] (1,3-dap = 1,3-diaminopropane): BET analysis and N₂/H₂O/D₂O adsorption studies†

Lei Liu,^a Chun-Yang Pan,

*^a Yong He,^a Li-Juan Zhong^a and Michael A. Beckett^b

Author affiliations

* Corresponding authors

^a School of Light Industry and Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, P.R. China
E-mail: panchuny@gdut.edu.cn

^b School of Natural Sciences, Bangor University, Gwynedd, UK

Abstract

A series of mono/bimetallic isostructural hybrid tetraborates of the general formula [Zn_xCo_(1−x)(1,3-dap)B₄O₇] has been prepared using a solvothermal method. Their adsorption/desorption curves for H₂O and D₂O demonstrate that these materials have a stronger affinity for H₂O than for D₂O and enrich the D₂O content of D₂O/H₂O mixtures.

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Article information

DOI: https://doi.org/10.1039/D4DT00117F
Article type: Paper
Submitted: 14 Jan 2024
Accepted: 02 Feb 2024
First published: 05 Feb 2024

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Dalton Trans., 2024,53, 4637-4642

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Co^(II)-doped hybrid Zn^(II) tetraborate complexes, [Zn_xCo_(1−x)(1,3-dap)B₄O₇] (1,3-dap = 1,3-diaminopropane): BET analysis and N₂/H₂O/D₂O adsorption studies

L. Liu, C. Pan, Y. He, L. Zhong and M. A. Beckett, Dalton Trans., 2024, 53, 4637 DOI: 10.1039/D4DT00117F

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