Issue 26, 2024

A mononuclear Fe(iii) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour

Abstract

AC susceptibility measurements of [FeIII(L5)(NCSe)] reveal a field supported slow magnetic relaxation. On cooling, the relaxation time of the high-frequency fraction decreases which is a sign of reciprocating thermal behaviour. The relaxation time for the low-frequency mode at T = 2.0 K is as high as τ(LF) = 2.0 s.

Graphical abstract: A mononuclear Fe(iii) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour

Supplementary files

Article information

Article type
Communication
Submitted
03 Mar 2024
Accepted
15 May 2024
First published
04 Jun 2024

Dalton Trans., 2024,53, 10824-10828

A mononuclear Fe(III) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour

T. Bridová, C. Rajnák, J. Titiš, E. Samoľová, K. Tran, O. Malina, A. Bieńko, F. Renz, M. Gembický and R. Boča, Dalton Trans., 2024, 53, 10824 DOI: 10.1039/D4DT00642A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements