Issue 22, 2024

Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis

Abstract

First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(IV) in concentrated (6.0 M) HNO3, and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO3˙ and Am(III).

Graphical abstract: Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis

Supplementary files

Article information

Article type
Communication
Submitted
04 Apr 2024
Accepted
09 May 2024
First published
22 May 2024

Dalton Trans., 2024,53, 9262-9266

Generation and study of Am(IV) by temperature-controlled electron pulse radiolysis

A. E. Kynman, T. S. Grimes, S. P. Mezyk, B. Layne, A. R. Cook, B. M. Rotermund and G. P. Horne, Dalton Trans., 2024, 53, 9262 DOI: 10.1039/D4DT00991F

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