Issue 31, 2024

Structure and redox behaviour of a paramagnetic Rh–Pt–Cu–Pt–Rh heterometallic-extended metal-atom chain

Abstract

A paramagnetic, pentanuclear, metal–metal bonded complex comprising three metals is isolated. The Cu dx2y2 orbital of the Rh–Pt–Cu–Pt–Rh chain contains an unpaired electron. The close energetic levels and symmetric overlap of the Cu dx2y2 and Rh–Pt δ* induces a charge-transfer reaction to achieve the diamagnetic Rh–Pt–Cu–Pt–Rh complex.

Graphical abstract: Structure and redox behaviour of a paramagnetic Rh–Pt–Cu–Pt–Rh heterometallic-extended metal-atom chain

Supplementary files

Article information

Article type
Communication
Submitted
17 Apr 2024
Accepted
17 Jul 2024
First published
19 Jul 2024

Dalton Trans., 2024,53, 12867-12871

Structure and redox behaviour of a paramagnetic Rh–Pt–Cu–Pt–Rh heterometallic-extended metal-atom chain

K. Uemura and Y. Ikeda, Dalton Trans., 2024, 53, 12867 DOI: 10.1039/D4DT01134A

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