Issue 28, 2024

Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes

Abstract

We disclose a novel series of N-heterocyclic carbene (NHC) gold complexes with varied steric and electronic properties, bearing fluorinated alkoxide anions. Early reactivity studies involving these synthons, lead to the synthesis of various complexes of relevance to gold chemistry and catalysis.

Graphical abstract: Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes

Supplementary files

Article information

Article type
Paper
Submitted
12 Jun 2024
Accepted
27 Jun 2024
First published
28 Jun 2024
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2024,53, 11952-11958

Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes

P. Arnaut, N. Bracho Pozsoni, F. Nahra, N. V. Tzouras and S. P. Nolan, Dalton Trans., 2024, 53, 11952 DOI: 10.1039/D4DT01402B

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