Investigation of SrB4O7:Tm2+ luminescence for temperature imaging with high sensitivity based on time-resolved luminescence

Abstract

In recent years, with the growing demand for non-contact and real-time optical temperature measurements, it has become imperative to develop new luminescent thermometry materials as well as novel temperature detection schemes with higher sensitivity. In this work, a series of Sr_1−xB₄O₇:xTm²⁺ (x = 0.001–0.01) polycrystalline powder samples were prepared using a high temperature solid state reaction under ambient atmospheric conditions. The emission spectra and the luminescence decay curves of the red emission corresponding to the 4f¹²5d → 4f¹³(²F_7/2) transition of Tm²⁺ were recorded at intervals of 10 K from 280 K to 380 K. Both the emission intensity and the fluorescence lifetime exhibited remarkable temperature correlation in the studied temperature range, which reached the best relative temperature sensitivities of 3.55% K⁻¹ and 3.86% K⁻¹ at 363 K and 346 K, respectively. Furthermore, taking into account the highly sensitive variation of the fluorescence lifetime of Tm²⁺ in the SrB₄O₇ matrix as the temperature increased near room temperature, a time-resolved temperature measurement scheme was performed to realize real-time temperature field imaging. By utilizing the intensified charge coupled device (ICCD) camera with a time gate to acquire the integral intensity of distinct time intervals and calibrate the relationship between the ratio and the temperature, the experimental results demonstrated that this temperature measurement scheme can achieve a maximum relative sensitivity of 9.39% K⁻¹ at 313 K, which significantly surpasses the relative sensitivity of the other two conventional temperature measurement schemes.