Issue 42, 2024

One ligand, two roles: novel pillar-layered metal–organic frameworks built with a 3D ligand and asymmetric inorganic nodes

Abstract

Herein, we show two cases of pillar-layered MOFs which are built solely with one kind of three-dimensional (3D) ditopic ligand. The ligand in both structures functions not only as an intralayer linker in the layer but also as a “pillar” between adjacent layers. Such multi-functionality of the linker is accompanied by uncommon asymmetric 10-c metal hexamer or 7-c tetramer nodes, which have never been reported in previous 3D MOF structures.

Graphical abstract: One ligand, two roles: novel pillar-layered metal–organic frameworks built with a 3D ligand and asymmetric inorganic nodes

Supplementary files

Article information

Article type
Communication
Submitted
17 Jul 2024
Accepted
13 Oct 2024
First published
14 Oct 2024

Dalton Trans., 2024,53, 17146-17150

One ligand, two roles: novel pillar-layered metal–organic frameworks built with a 3D ligand and asymmetric inorganic nodes

C. Xue, Y. Zhang, K. Zhu, S. Deng, K. Qu, S. Gong and H. Yang, Dalton Trans., 2024, 53, 17146 DOI: 10.1039/D4DT02061H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements