Pd NPs decorated on crosslinked sodium alginate modified iron-based metal–organic framework Fe(BTC) as a green multifunctional catalyst for the oxidative amidation

Abstract

The primary objective of this investigation was to develop a new nanocatalyst that could produce amides by oxidative amidation of benzyl alcohol, thereby reducing its environmental harm. To achieve this, Pd nanoparticle-immobilized crosslinked sodium alginate-modified iron-based metal–organic framework Fe(BTC) (Fe(BTC)@SA/ED/Pd), with excellent activity and selectivity in modified oxidative amidation of benzyl alcohol with amines, has been described. Crosslinked sodium alginate was modified on iron-based metal–organic framework Fe(BTC). It is worth noting that Pd nanoparticles were immobilized for the first time on a novel nanocomposite based on the Fe(BTC) MOF and crosslinked sodium alginate for tandem oxidative amidation to improve the eco-friendliness and economic efficiency of the process. The synergic effects of Fe(BTC), sodium alginate, and Pd NPs are important factors influencing the catalytic activity. Easy and green synthesis methods, availability of materials, high Pd loading, available catalytic sites, high surface area, high selectivity, and simple separation from the reaction medium are effective properties in catalytic activity.