Issue 3, 2024

Palladium-catalyzed α-arylation/β-elimination of sulfones

Abstract

Here, we disclose a palladium-catalyzed cross-coupling reaction of benzylic sulfones with aryl triflates for the synthesis of 1,1-diarylethylenes. This palladium-catalyzed transformation tolerates various benzylic sulfones, especially heteroaromatic-substituted sulfones, with good to excellent yields.

Graphical abstract: Palladium-catalyzed α-arylation/β-elimination of sulfones

Supplementary files

Article information

Article type
Communication
Submitted
07 Oct 2023
Accepted
11 Dec 2023
First published
11 Dec 2023

New J. Chem., 2024,48, 1062-1066

Palladium-catalyzed α-arylation/β-elimination of sulfones

M. Yu, L. Duan, X. Zhang, Q. Zhang, H. Wang and X. Huang, New J. Chem., 2024, 48, 1062 DOI: 10.1039/D3NJ04668K

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