Performance analysis and structure characterization of polylactic acid modified with three flame retardants

Abstract

In this paper, flame retardant composites were prepared by incorporating three flame retardants (FRs), including triphenyl phosphate (TPP), polysiloxane (PSQ) and phosphite functionalized polysiloxane (PPSQ), respectively into a polylactic acid (s/PLLA) matrix. The results indicated that the ultimate oxygen index increased from 20.6% (s/PLLA) to 22.5% (s/PLLA/TPP), 21.1% (s/PLLA/PSQ), and 23.3% (s/PLLA/PPSQ). The composites exhibited a decrease in peak heat release rate (pHRR) and prolonged peak time according to the cone calorimetry analysis. s/PLLA/PPSQ possessed the highest residual carbon content and the densest char residue with finest and smallest pores, indicating excellent flame-retardant performance. The crystallization behavior analysis revealed that the three FRs resulted in an increased crystallization rate and crystallinity. Notably, the crystallinity of s/PLLA/PPSQ increased from 25.8% in s/PLLA to 37.3%. Additionally, PSQ and PPSQ effectively enhanced the mechanical properties of composite materials. Compared to s/PLLA, the tensile strength of s/PLLA/PSQ and s/PLLA/PPSQ increased by 11.5% and 31.3% respectively, and storage modulus increased by 50.0% and 14.6%. This research demonstrated that among the three additives, PPSQ can effectively provide both flame retardancy and mechanical properties to the s/PLLA matrix, resulting in the composite with the best comprehensive performance.