Issue 28, 2024

Nanosized Chevrel phases for dendrite-free zinc–ion based energy storage: unraveling the phase transformations

Abstract

The nanoscale form of the Chevrel phase, Mo6S8, is demonstrated to be a highly efficient zinc-free anode in aqueous zinc ion hybrid supercapacitors (ZIHSCs). The unique morphological characteristics of the material when its dimensions approach the nanoscale result in fast zinc intercalation kinetics that surpass the ion transport rate reported for some of the most promising materials, such as TiS2 and TiSe2. In situ Raman spectroscopy, post-mortem X-ray diffraction, Hard X-ray photoelectron spectroscopy, and density functional theory (DFT) calculations were combined to understand the overall mechanism of the zinc ion (de)intercalation process. The previously unknown formation of the sulfur-deficient Zn2.9Mo15S19 (Zn1.6Mo6S7.6) phase is identified, leading to a re-evaluation of the mechanism of the (de)intercalation process. A full cell comprised of an activated carbon (YEC-8A) positive electrode delivers a cell capacity of 38 mA h g−1 and an energy density of 43.8 W h kg−1 at a specific current density of 0.2 A g−1. The excellent cycling stability of the device is demonstrated for up to 8000 cycles at 3 A g−1 with a coulombic efficiency close to 100%. Post-mortem microscopic studies reveal the absence of dendrite formation at the nanosized Mo6S8 anode, in stark contrast to the state-of-the-art zinc electrode.

Graphical abstract: Nanosized Chevrel phases for dendrite-free zinc–ion based energy storage: unraveling the phase transformations

Supplementary files

Article information

Article type
Paper
Submitted
20 Mar 2024
Accepted
20 Jun 2024
First published
20 Jun 2024
This article is Open Access
Creative Commons BY license

Nanoscale, 2024,16, 13597-13612

Nanosized Chevrel phases for dendrite-free zinc–ion based energy storage: unraveling the phase transformations

A. Elgendy, A. A. Papaderakis, A. Ejigu, K. Helmbrecht, B. F. Spencer, A. Groß, A. S. Walton, D. J. Lewis and R. A. W. Dryfe, Nanoscale, 2024, 16, 13597 DOI: 10.1039/D4NR01238K

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