Issue 11, 2024

Effects of stirring rate on morphology of aqueous RAFT emulsion PISA-derived block copolymer nanoparticles

Abstract

The influence of stirring rate on nanoparticle morphology in aqueous RAFT emulsion PISA has been investigated using the macroRAFT agents poly(poly(ethylene)glycol methyl ether acrylate)-TTC and poly(poly(ethylene glycol) methyl ether methacrylate)-TTC chain extended with styrene/n-butyl acrylate (copolymer) and methyl methacrylate (MMA), respectively. The influence of temperature was first investigated by conducting polymerizations at 50 °C and 70 °C for the MMA system, revealing that formation of high-order morphologies is facilitated at 70 °C. The influence of stirring rate was explored for both systems, showing that the extent of influence depends on the polymerization temperature. At 50 °C, high-order morphologies were obtained only at moderate stirring rate whereas at 70 °C, high-order morphologies were observed across a much wider range of stirring rates. The present results demonstrate that both polymerization temperature and stirring rate can significantly affect the self-assembly process in PISA.

Graphical abstract: Effects of stirring rate on morphology of aqueous RAFT emulsion PISA-derived block copolymer nanoparticles

Supplementary files

Article information

Article type
Paper
Submitted
30 Nov 2023
Accepted
09 Feb 2024
First published
09 Feb 2024

Polym. Chem., 2024,15, 1102-1111

Effects of stirring rate on morphology of aqueous RAFT emulsion PISA-derived block copolymer nanoparticles

H. J. Kim, F. Ishizuka, J. Li, R. P. Kuchel, S. Chatani, H. Niino and P. B. Zetterlund, Polym. Chem., 2024, 15, 1102 DOI: 10.1039/D3PY01318A

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