Rheological and radioactive decontamination properties of ethyl cellulose sols in green solvents at a temperature below 0 °C

Abstract

Strippable film decontamination has been considered one of the best prospects for radioactive surface decontamination due to its high decontamination effect and less secondary pollution. However, research into strippable films has until now focused on radioactive decontamination at room temperature. Therefore, it is vital to seek a suitable degradable material for preparing strippable films in removing contaminants in an extremely cold region, as it will face the problem of the freezing of the detergent. Ethyl cellulose (EC) is a kind of degradable biopolymer which is easily dissolved in volatile green organic solvents to form a sol below 0 °C which is advantageous for forming a film. Therefore, it would be the best choice for preparing a strippable film detergent. In this study, EC sols were obtained by placing EC powder into the green solvents anhydrous ethanol and ethyl acetate. The steady and dynamic rheological behavior of EC sols was investigated with a rotary rheometer with the temperature ranging from −10 °C to 0 °C to disclose their spraying performance. Moreover, the radioactive decontamination effect of EC sols and the mechanism were also investigated. The results showed that the EC sols were pseudoplastic fluids which obeyed the Ostwald–de Waele power law below 0 °C. Furthermore, the viscosity of EC sols could be reduced by stirring, which is convenient for large-area spraying during decontamination below 0 °C. At −10 °C, the comprehensive decontamination rates of all plates were over 85%. Therefore, EC sols could be used as a basic material for strippable film decontamination below 0 °C.