Issue 4, 2024

Organocatalytic activation of hydrogen peroxide: towards green and sustainable oxidations

Abstract

The advent of organocatalysis provided an additional option in every researcher's arsenal, towards the development of elegant and sustainable protocols for various organic transformations. Oxidation reactions are considered to be key in organic synthesis since oxygenated functionalities appear in many natural products. Hydrogen peroxide is categorized as a green oxidant, since its only by-product is water, offering novel opportunities for the development of green and sustainable protocols. In this review article, we intend to present recent developments in the field of the organocatalytic activation of hydrogen peroxide, providing useful insight into the applied oxidative protocols. At the same time, we will present some interesting mechanistic studies, providing information on the oxygen transfer processes.

Graphical abstract: Organocatalytic activation of hydrogen peroxide: towards green and sustainable oxidations

Article information

Article type
Perspective
Submitted
21 Oct 2023
Accepted
15 Dec 2023
First published
18 Dec 2023
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2024,15, 1177-1203

Organocatalytic activation of hydrogen peroxide: towards green and sustainable oxidations

E. T. Poursaitidis, P. L. Gkizis, I. Triandafillidi and C. G. Kokotos, Chem. Sci., 2024, 15, 1177 DOI: 10.1039/D3SC05618J

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