Strong-field effects in the photo-induced dissociation of the hydrogen molecule on a silver nanoshell

Abstract

Plasmonic catalysis is a rapidly growing field of research, both from experimental and computational perspectives. Experimental observations demonstrate an enhanced dissociation rate for molecules in the presence of plasmonic nanoparticles under low-intensity visible light. The hot-carrier transfer from the nanoparticle to the molecule is often claimed as the mechanism for dissociation. However, the charge transfer time scale is on the order of a few femtoseconds and cannot be resolved experimentally. In this situation, ab initio non-adiabatic calculations can provide a solution. Such simulations, however, have their own limitations related to the computational cost. To accelerate plasmonic catalysis simulations, many researchers resort to applying high-intensity external fields to nanoparticle-molecule systems. Here, we show why such an approach can be problematic and emphasize the importance of considering strong-field effects when interpreting the results of time-dependent density functional theory simulations of plasmonic catalysis. By studying the hydrogen molecule dissociation on the surface of a silver nanoshell and analyzing the electron transfer at different field frequencies and high intensities, we demonstrate that the molecule dissociates due to multiphoton absorption and subsequent ionization.