Issue 42, 2024

An electron-losing regulation strategy for stripping modulation towards a highly reversible Zn anode

Abstract

The practical application of aqueous zinc-ion batteries (AZIBs) is hindered by their low coulombic efficiency (CE) and unstable cycle life. Numerous electrolyte-additive-related studies have been performed, but most of the focus has been on the Zn plating process. In fact, practical AZIBs undergo stripping in practice rather than plating in the initial cycle, because the commonly used cathodes in the charged state do not have zinc ions, so a uniform stripping process is crucial for the cell performance of AZIBs. Here, we propose an electron-losing regulation strategy for stripping modulation by adding additives. Oxolane (OL) was chosen as the model additive to verify this assumption. It is found that OL adsorbs onto the uneven initial Zn surface and accelerates the dissolution of the Zn tips, thus providing a uniform Zn anode during the stripping process. The oxygen atoms in OL reduce the surface energy of Zn and promote the exposure of the Zn (002) surface during plating. Consequently, cells with the OL electrolyte additive maintained a long lifespan and showed superior reversibility with a high average CE. The findings of this work lead to a deep understanding of the underlying mechanism of Zn anode stripping and provide new guidance for designing electrolyte additives.

Graphical abstract: An electron-losing regulation strategy for stripping modulation towards a highly reversible Zn anode

Supplementary files

Article information

Article type
Edge Article
Submitted
11 Jul 2024
Accepted
19 Sep 2024
First published
20 Sep 2024
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2024,15, 17348-17361

An electron-losing regulation strategy for stripping modulation towards a highly reversible Zn anode

X. Wang, L. Liu, Z. Hu, C. Han, X. Xu, S. Dou and W. Li, Chem. Sci., 2024, 15, 17348 DOI: 10.1039/D4SC04611K

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