Cation migration in layered oxide cathodes for sodium-ion batteries: fundamental failure mechanisms and practical modulation strategies

Abstract

Sodium-ion batteries (SIBs) are regarded as competitive candidates for the next generation of electrochemical energy storage (EES) systems due to their low cost and abundant sodium resources. Layered oxide cathodes have attracted much interest owing to their simple preparation process, high specific capacity and environmental friendliness. However, undesired cation migration during electrochemical reactions can lead to irreversible phase transitions and structural degradation of layered oxide cathode materials, resulting in a sharp decrease in specific capacity and energy density. Therefore, in order to find effective strategies to suppress cation migration, the fundamental failure mechanism of layered oxides and the practical approaches to solve this key scientific issue are thoroughly investigated, and herein the history and current status of developments in this field are also reviewed. Elemental doping and structural design can directionally modify the electronic structure, energy band structure and electronic density of states in layered oxides and enhance cation migration barriers, which benefits the improvement of electrochemical performance and structural stability during the whole sodiation/desodiation process. The summary and prospects of inhibiting cation migration in layered oxides provide insights into the development of advanced cathode materials with high energy density and excellent structural stability for the commercialization of SIBs.