Issue 20, 2024

Inducing hollow and porous hematite nanorod photoanodes by rare earth and transition metal doping for enhanced solar water splitting

Abstract

Hematite serves as a promising photoanode material in photoelectrochemical (PEC) water splitting systems. However, its inherent limitations of short hole diffusion length and insufficient carrier lifetime pose a significant challenge for practical application. Here, we report a hollow and porous hematite nanorod photoanode using hybrid microwave annealing induced rare earth europium (Eu) and transition metal niobium (Nb)-doped core/shell FeOOH nanorods synthesized by a two-step hydrothermal method, which enhances photocurrent density (Jph) and reduces turn-on voltage (Von) simultaneously by three synergistic effects: (i) hollow and porous nanorod formation to shorten hole diffusion distance; (ii) surface asymmetric oxygen vacancies and Eu3+ ↔ Eu2+ states to generate highly active sites; and (iii) suppression of surface segregation of Nb and Sn to reduce surface states. As a result, the hollow and porous Eu, Nb co-doped Fe2O3 photoanode loaded with a RuFe2(OH)x cocatalyst achieves a Jph of 3.49 mA cm−2 and a Von of 0.67 VRHE under simulated 1 sun irradiation (100 mW cm−2), which is 2 times higher Jph and a more negative Von of ∼250 mV than that of Nb : Fe2O3. This work demonstrates the successful combination of the two-step hydrothermal method, rare earth and transition metal co-doping, and hybrid microwave annealing to design and construct efficient nanorod-based photoanodes.

Graphical abstract: Inducing hollow and porous hematite nanorod photoanodes by rare earth and transition metal doping for enhanced solar water splitting

Supplementary files

Article information

Article type
Communication
Submitted
24 Feb 2024
Accepted
30 Apr 2024
First published
30 Apr 2024

J. Mater. Chem. A, 2024,12, 11831-11840

Inducing hollow and porous hematite nanorod photoanodes by rare earth and transition metal doping for enhanced solar water splitting

C. Xu, H. Wang, K. Liang, Y. Zhang, W. Li and H. Zhang, J. Mater. Chem. A, 2024, 12, 11831 DOI: 10.1039/D4TA01258E

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