Surface modification unleashes light emitting applications of APbX3 perovskite nanocrystals

Abstract

Engineering the surface of metal halide perovskite nanocrystals (MHPNCs) is crucial for optimizing their optical properties, repairing surface defects, enhancing quantum yield, and ensuring long-term stability. These enhancements make surface-engineered MHPNCs ideal for applications in light-emitting devices (LEDs), displays, lasers, and photodetectors, contributing to energy efficiency. This article delves into an introduction to MHPNCs, their structure and types, particularly the ABX₃ type (where A represents monovalent organic/inorganic cations, B represents divalent metal ions mainly Pb metal, and X represents halide ions), synthesis methods, unique optical properties, surface modification techniques using various agents (particularly inorganic molecules/materials, organic molecules, polymers, and biomolecules) to tune optical properties and applications in the aforementioned light-emitting technologies, challenges and opportunities, including advantages and disadvantages of surface-modified APbX₃ MHPNCs, and a summary and future outlook. This article explores surface modification strategies to improve the optical performance of MHPNCs and aims to inspire advancements in light emitting applications. Importantly, the challenges and opportunities section of this article will illuminate the path to overcoming obstacles, providing invaluable insights for researchers in this field. This in-depth review explores the surface engineering of MHPNCs for light-emitting applications, highlighting their notable advantages and addressing ongoing challenges. By delving deep into various surface modification strategies, this article aims to revolutionize MHPNC-based light-emitting applications, setting a new benchmark in the field. This paves the way for revolutionary advancements, maximizing the capabilities of surface-engineered MHPNCs and heralding a transformative era in precise light-emitting research.