A sandwich-like heterometallic Fe7Sn6 oxo cluster constructed by tessellation of an Anderson-like {Fe7} wheel for near-infrared photothermal conversion

Xiu-Juan Tian; Qian Lu; Shi-Li Li; Xian-Ming Zhang

doi:10.1039/D4CC05796A

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A sandwich-like heterometallic Fe₇Sn₆ oxo cluster constructed by tessellation of an Anderson-like {Fe₇} wheel for near-infrared photothermal conversion†

Xiu-Juan Tian,‡^a Qian Lu,‡^a Shi-Li Li

*^a and Xian-Ming Zhang

*^ab

Author affiliations

* Corresponding authors

^a Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, College of Chemistry & Material Science, Shanxi Normal University, Taiyuan 030031, P. R. China
E-mail: lisl@sxnu.edu.cn, zhangxm@dns.sxnu.edu.cn

^b College of Chemistry & Chemical Engineering, Taiyuan University of Technology, Taiyuan, P. R. China
E-mail: zhangxianming@tyut.edu.cn

Abstract

Herein we report a unique sandwich-like heterometallic Fe₇Sn₆ oxo cluster, which features an Anderson-type {Fe₇} wheel sandwiched by two {Sn₃} layers and is formed via the coordination-induced effect of 2,6-pyridinedicarboxylate. The highly efficient photothermal conversion capability and excellent photothermal stability of Fe₇Sn₆ demonstrate the potential for solar energy conversion.

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Article information

DOI: https://doi.org/10.1039/D4CC05796A
Article type: Communication
Submitted: 30 Oct 2024
Accepted: 09 Dec 2024
First published: 10 Dec 2024

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Chem. Commun., 2025,61, 1140-1143

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A sandwich-like heterometallic Fe₇Sn₆ oxo cluster constructed by tessellation of an Anderson-like {Fe₇} wheel for near-infrared photothermal conversion

X. Tian, Q. Lu, S. Li and X. Zhang, Chem. Commun., 2025, 61, 1140 DOI: 10.1039/D4CC05796A

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