Photo-induced nitroxyl anion/HNO release from a nitrosyl complex of Mn(II)–porphyrinate

Shankhadeep Saha; Sayani Maity; Bapan Samanta; Riya Ghosh; Kalishankar Bhattacharyya; Biplab Mondal

doi:10.1039/D4CC06203E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Photo-induced nitroxyl anion/HNO release from a nitrosyl complex of Mn(ii)–porphyrinate†

Shankhadeep Saha,^a Sayani Maity,^a Bapan Samanta,^a Riya Ghosh,^a Kalishankar Bhattacharyya

^a and Biplab Mondal

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039, India
E-mail: biplab@iitg.ac.in

Abstract

A nitrosyl complex of Mn^II–porphyrinate, 1 has been synthesized and characterized. It was found to donate a nitroxyl anion (NO⁻) to suitable acceptors in dichloromethane solution in the presence of visible light. The evolution of N₂O and the characteristic reaction with PPh₃ in the presence of H⁺ confirms the NO⁻/HNO donation.

This article is part of the themed collection: Small Molecule Transformations of Energy Relevance

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D4CC06203E
Article type: Communication
Submitted: 22 Nov 2024
Accepted: 29 Dec 2024
First published: 02 Jan 2025

Download Citation

Chem. Commun., 2025,61, 2353-2356

Permissions

Request permissions

Photo-induced nitroxyl anion/HNO release from a nitrosyl complex of Mn(II)–porphyrinate

S. Saha, S. Maity, B. Samanta, R. Ghosh, K. Bhattacharyya and B. Mondal, Chem. Commun., 2025, 61, 2353 DOI: 10.1039/D4CC06203E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Photo-induced nitroxyl anion/HNO release from a nitrosyl complex of Mn(ii)–porphyrinate†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Photo-induced nitroxyl anion/HNO release from a nitrosyl complex of Mn(II)–porphyrinate

Social activity

Search articles by author

Spotlight

Advertisements