A vinylene-linked diketopyrrolopyrrole-based covalent organic framework for photocatalytic oxidation reactions†
Abstract
A vinylene-linked DPP-COF with an ultra-narrow bandgap of 1.06 eV was reported. This COF demonstrates high chemical stability and significant charge transfer properties, and was applied to the photooxidation of sulfides and tetrahydroisoquinolines, exhibiting exceptional photoactivities.