Reactions of boradigermaallyl, which can also be regarded as a chloroborylene stabilzed by two germylene donors, with thiophene, furan, pyridazine and 2,2′-bipyridine are presented. Insertion of the boron atom into the heterocycles is observed and the resulting heterocycles continue to react with the bis(germylene) molecule.
R. H. Kern, P. L. Schmiedel, H. Schubert and L. Wesemann, Chem. Commun., 2025, 61, 4844 DOI: 10.1039/D5CC00639B
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