Sulfonated reduced graphene oxide encapsulated perovskite-type ErCoFe oxide nanoparticles for efficient electrochemical water oxidation

Abstract

Perovskite oxides play a vital role as electrocatalysts in water oxidation due to their flexible and unique electronic structures. In this work, Er-based perovskites ErCo_1−xFe_xO_3−δ (x = 0.0, 0.1, 0.3, 0.5, 0.7, and 1.0) denoted as EC, ECF-0.9, ECF-0.7, ECF-0.5, ECF-0.3, and EF, respectively, are synthesized by the sol–gel method. Then, ECF-0.9 is supported on sulfonated reduced graphene oxide (S-rGO) by a hydrothermal method, with weight ratios of 1 : 1 and 3 : 1 of ECF/0.9 to S-rGO (shown as ECF-0.9/S-rGO(50%) and ECF-0.9/S-rGO(75%), respectively). The structural properties and the morphology of the synthesized materials are studied using a series of different techniques. The prepared perovskites are then used as electrode materials for electrochemical water oxidation. ECF-0.9 reveals better activity than pure EF, EC, and other perovskite oxides in terms of overpotential, Tafel slope, electrochemically active surface area (ECSA), and charge transfer resistance (R_ct) values. Interestingly, when the optimized perovskite oxide catalyst ECF-0.9 is decorated on S-rGO sheets, the water oxidation activity is significantly improved. ECF-0.9/S-rGO(75%) exhibits superior activity for water oxidation with an overpotential of 290 mV@10 mA cm⁻² and a Tafel slope of 41 mV dec⁻¹. Finally, overall water splitting with ECF-0.9/S-rGO(75%) as the anode electrode shows a low electrolysis voltage of 1.60 V, alongside excellent stability for 20 h.