The isolation of a stable persistent carbazole-stabilized boron-centered monoradical anion 1˙−, which has a high spin density at the B atom, has been reported. It is characterized using the crystal structure and UV-vis absorption spectrum, as well as electron paramagnetic resonance spectroscopy. Interestingly, the B–N bond was activated by the boron-centered radical anion 1˙−, which had not been reported before.
N. Yuan, T. Zhu, J. Ma, Y. Xue and Y. Liu, Dalton Trans., 2025, 54, 2257 DOI: 10.1039/D4DT03314K
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