Expanding silver fluorooxoborate crystal chemistry: Ag2B5O8F with 3D double interpenetrating frameworks and Ag3B5O8F2 with 2D layers

Sergey Volkov; Xia Yang; Vadim Kireev; Alexander Banaru; Shujuan Han; Alevtina Gosteva; Maxim Arsent'ev; Dmitri Charkin; Alexey Povolotskiy; Yevgeny Savchenko; Maria Krzhizhanovskaya; Stepan Vorobiev; Yulia Vaitieva; Sergey Aksenov; Fangfang Zhang

doi:10.1039/D5DT00263J

Expanding silver fluorooxoborate crystal chemistry: Ag₂B₅O₈F with 3D double interpenetrating frameworks and Ag₃B₅O₈F₂ with 2D layers†

Sergey Volkov,

‡^ab Xia Yang,‡^a Vadim Kireev,^b Alexander Banaru,

^cb Shujuan Han,

*^a Alevtina Gosteva,^de Maxim Arsent'ev,

^fb Dmitri Charkin,^cb Alexey Povolotskiy,^g Yevgeny Savchenko,

^hi Maria Krzhizhanovskaya,^j Stepan Vorobiev,^f Yulia Vaitieva,^b Sergey Aksenov

^bh and Fangfang Zhang

*^a

Author affiliations

* Corresponding authors

^a Research Center for Crystal Materials, CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, CAS, Urumqi, China
E-mail: ffzhang@ms.xjb.ac.cn

^b Laboratory of Arctic Mineralogy and Material Sciences, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

^c Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia

^d I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

^e Federal State Autonomous Educational Institution of Higher Education “Murmansk Arctic University”, Murmansk 183038, Russia

^f Infochemistry Scientific Center (ISC), ITMO University, St. Petersburg, Russia

^g Institute of Chemistry, Saint Petersburg State University, St. Petersburg, Russia

^h Geological Institute, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

ⁱ Nanomaterials Research Centre, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

^j Saint Petersburg State University, St. Petersburg, Universitetskaya Emb. 7/9, 199034, Russia

Abstract

The rapid development of the chemistry of fluorooxoborates is associated with their important role as valuable optical materials. In this work, we report the first two silver representatives of the family, Ag₂B₅O₈F (1) and Ag₃B₅O₈F₂ (2). Both structures are based on pentaborate groups with different degrees of “fluorination”: 1 contains interpenetrating frameworks composed of [B₅O₁₀F] fundamental building units, while 2 consists of layers of [B₅O₁₀F₂].

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Expanding silver fluorooxoborate crystal chemistry: Ag₂B₅O₈F with 3D double interpenetrating frameworks and Ag₃B₅O₈F₂ with 2D layers†

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Expanding silver fluorooxoborate crystal chemistry: Ag₂B₅O₈F with 3D double interpenetrating frameworks and Ag₃B₅O₈F₂ with 2D layers

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