Issue 4, 2025
From the journal:

New Journal of Chemistry

Comparable syntheses of terminal aluminum selenide and telluride†

Bin Li, ORCID logo *a   Yuanyuan Wang,a   Sonam Suthar, ORCID logo b   Manbo Zhanga  and  Kartik Chandra Mondal ORCID logo *b  

* Corresponding authors

a Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Key Laboratory of Light Energy Conversion Materials of Hunan Province, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China
E-mail: binli@hunnu.edu.cn

b Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India
E-mail: csdkartik@iitm.ac.in

Abstract

The β-diketiminate bonded Al(I)-compound (L)Al (L = HC{C(Me)N(Ar)}2, Ar = 2,6-iPr2C6H3) reacted with the C[double bond, length as m-dash]E (E = Se, Te) bonds of N-heterocyclic selenourea and tellurourea (iPrNHC[double bond, length as m-dash]E) to exclusively afford [(LAl(iPrNHC)[double bond, length as m-dash]E)] (E = Se, 1; Te, 2), respectively. Structural and spectroscopic characterizations were done, and the bonding details were experimentally and theoretically studied.

Graphical abstract: Comparable syntheses of terminal aluminum selenide and telluride

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Article information

DOI
https://doi.org/10.1039/D4NJ04255G
Article type
Communication
Submitted
30 Sep 2024
Accepted
06 Dec 2024
First published
26 Dec 2024

New J. Chem., 2025,49, 1133-1137

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Comparable syntheses of terminal aluminum selenide and telluride

B. Li, Y. Wang, S. Suthar, M. Zhang and K. C. Mondal, New J. Chem., 2025, 49, 1133 DOI: 10.1039/D4NJ04255G

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