Linking the pyramid distortion to luminescence in Sb-based metal halide by best fitted ideal polyhedron characterization

Yunfeng Fang; Yuchen Zhang; Leopoldo Suescun; Mingyue Chen; Zhen Song; Quanlin Liu

doi:10.1039/D5TC00556F

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Linking the pyramid distortion to luminescence in Sb-based metal halide by best fitted ideal polyhedron characterization†

Yunfeng Fang,^a Yuchen Zhang,^a Leopoldo Suescun,

^b Mingyue Chen,^a Zhen Song

*^a and Quanlin Liu

*^a

Author affiliations

* Corresponding authors

^a The Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, China
E-mail: zsong@ustb.edu.cn, qlliu@ustb.edu.cn

^b Cryssmat-Lab/DETEMA, Facultad de Química, Universidad de la República, Av. General Flores 2124, Montevideo 11800, Uruguay

Abstract

Sb-based metal halides have been a research focus because of their excellent optical properties. Pyramid-like [SbCl₅] polyhedra are the most distinct crystallographic feature. We analyzed 56 luminescent Sb-based hybrids from a list of 120 Sb chlorides by finding the corresponding best fitted ideal polyhedron. The results show a significant correlation between the distortion and photoluminescent quantum yield.

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Article information

DOI: https://doi.org/10.1039/D5TC00556F
Article type: Communication
Submitted: 10 Feb 2025
Accepted: 03 Mar 2025
First published: 05 Mar 2025

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J. Mater. Chem. C, 2025,13, 5988-5992

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Linking the pyramid distortion to luminescence in Sb-based metal halide by best fitted ideal polyhedron characterization

Y. Fang, Y. Zhang, L. Suescun, M. Chen, Z. Song and Q. Liu, J. Mater. Chem. C, 2025, 13, 5988 DOI: 10.1039/D5TC00556F

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Journal of Materials Chemistry C

Linking the pyramid distortion to luminescence in Sb-based metal halide by best fitted ideal polyhedron characterization†

Abstract

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Linking the pyramid distortion to luminescence in Sb-based metal halide by best fitted ideal polyhedron characterization

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