Issue 18, 2001
From the journal:

Chemical Communications

One-step synthesis and redox properties of dodecahydro-3a,9a-diazaperylene—the most easily oxidizedp-phenylenediamine

Abdel Monem M. Rawashdeh,a   Chariklia Sotiriou-Leventis,*a   Xuerong Gaoa  and  Nicholas Leventis*a  

* Corresponding authors

a Department of Chemistry, University of Missouri-Rolla, Rolla, USA.
E-mail: cslevent@umr.edu (CSL);, leventis@umr.edu (NL);
Fax: +1 573 341 6033;
Tel: +1 573 341 4353(CSL);

Abstract

Dodecahydro-3a,9a-diazaperylene (DHDAP) was prepared in one step from p-phenylenediamine and 1-bromo-3-chloropropane, and its first redox potential is 292 mV more negative than the first redox potential of N,N,N′,N′-tetramethyl-p-phenyl enediamine (TMPD), thus becoming the most easily oxidized p-phenylenediamine homologue.

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Article information

DOI
https://doi.org/10.1039/B104991G
Article type
Communication
Submitted
29 May 2001
Accepted
17 Jul 2001
First published
29 Aug 2001

Chem. Commun., 2001, 1742-1743

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One-step synthesis and redox properties of dodecahydro-3a,9a-diazaperylene—the most easily oxidized p-phenylenediamine

A. M. M. Rawashdeh, C. Sotiriou-Leventis, X. Gao and N. Leventis, Chem. Commun., 2001, 1742 DOI: 10.1039/B104991G

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