Issue 30, 2005
From the journal:

Chemical Communications

Structure and reactivity of a new anionic N-heterocyclic carbene silver(i) complex†

Claude Y. Legault,a   Christopher Kendalla  and  André B. Charette*a  

* Corresponding authors

a Département de Chimie, Université de Montréal, P.O. Box 6128, Station Downtown, Montréal, QC, Canada
E-mail: andre.charette@umontreal.ca
Fax: +1 514 343 5900
Tel: +1 514 343 6283

Abstract

The efficient synthesis of aN-benzoyliminoimidazolium ylide provides access to a new type of N-hetereocyclic anionic carbene, from which air stable Ag(I) and Cu(II) complexes and a catalytically active Rh(I) complex were formed.

Graphical abstract: Structure and reactivity of a new anionic N-heterocyclic carbene silver(i) complex

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Article information

DOI
https://doi.org/10.1039/B506232B
Article type
Communication
Submitted
24 Mar 2005
Accepted
01 Jun 2005
First published
01 Jul 2005

Chem. Commun., 2005, 3826-3828

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Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex

C. Y. Legault, C. Kendall and A. B. Charette, Chem. Commun., 2005, 3826 DOI: 10.1039/B506232B

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