First iron-catalyzed synthesis of oximes from styrenes

Saisuree Prateeptongkum; Irina Jovel; Ralf Jackstell; Nadine Vogl; Christoph Weckbecker; Matthias Beller

doi:10.1039/B900326F

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First iron-catalyzed synthesis of oximes from styrenes†‡

Saisuree Prateeptongkum,^a Irina Jovel,^a Ralf Jackstell,^a Nadine Vogl,^b Christoph Weckbecker^b and Matthias Beller*^a

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* Corresponding authors

^a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, Rostock, Germany
E-mail: matthias.beller@catalysis.de
Fax: +49-381-1281-51113

^b Evonik Degussa GmbH, Health and Nutrition, Rodenbacher Chaussee 4, Hanau, Germany

Abstract

Aryl-substituted olefins react with t-butyl nitrite and sodium borohydride in the presence of iron(II)phthalocyanine to give oximes in moderate to high yields.

This article is part of the themed collection: Selective Catalysis for Organic Synthesis

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Supplementary files

General procedure, characterization data for compounds 2, 4a–4k and 5 and ¹H and ¹³C NMR spectra of compounds 2, 4a–4k and 5 PDF (4494K)

Article information

DOI: https://doi.org/10.1039/B900326F
Article type: Communication
Submitted: 07 Jan 2009
Accepted: 02 Feb 2009
First published: 25 Feb 2009

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Chem. Commun., 2009, 1990-1992

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First iron-catalyzed synthesis of oximes from styrenes

S. Prateeptongkum, I. Jovel, R. Jackstell, N. Vogl, C. Weckbecker and M. Beller, Chem. Commun., 2009, 1990 DOI: 10.1039/B900326F

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Chemical Communications

First iron-catalyzed synthesis of oximes from styrenes†‡

Abstract

Supplementary files

Article information

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First iron-catalyzed synthesis of oximes from styrenes

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