Issue 24, 2009
From the journal:

Chemical Communications

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes†‡

Takahiro Kawamoto,a   Sho Hirabayashi,a   Xun-Xiang Guo,a   Takahiro Nishimura*a  and  Tamio Hayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Japan
E-mail: tnishi@kuchem.kyoto-u.ac.jp, thayashi@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3983
Tel: +81 75 753 3988

Abstract

The rhodium-catalyzed intermolecular asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes gave chiral allylicphosphine oxides substituted with vinylether and thioether moieties in high yields with high enantioselectivities.

Graphical abstract: Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

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Article information

DOI
https://doi.org/10.1039/B900976K
Article type
Communication
Submitted
16 Jan 2009
Accepted
17 Feb 2009
First published
13 Mar 2009

Chem. Commun., 2009, 3528-3530

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Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

T. Kawamoto, S. Hirabayashi, X. Guo, T. Nishimura and T. Hayashi, Chem. Commun., 2009, 3528 DOI: 10.1039/B900976K

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