Issue 14, 2011
From the journal:

Chemical Communications

Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand†

Manuela Stefanelli,a   Sara Nardis,a   Luca Tortora,a   Frank R. Fronczek,b   Kevin M. Smith,b   Silvia Licocciaa  and  Roberto Paolesse*a  

* Corresponding authors

a Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata”, via della Ricerca Scientifica 1, 00133 Rome, Italy
E-mail: paolesse@uniroma2.it
Fax: +39 06 72594328
Tel: +39 06 72594752

b Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA

Abstract

Mono- and di-substituted β-nitro derivatives have been obtained from the reaction of ttcorrFeCl with sodium nitrite in refluxing DMF. This result is unprecedented for iron corrolates and further evidences the non-innocent character of the corrole ligand.

Graphical abstract: Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand

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Article information

DOI
https://doi.org/10.1039/C0CC05491G
Article type
Communication
Submitted
10 Dec 2010
Accepted
07 Feb 2011
First published
07 Mar 2011

Chem. Commun., 2011,47, 4255-4257

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Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand

M. Stefanelli, S. Nardis, L. Tortora, F. R. Fronczek, K. M. Smith, S. Licoccia and R. Paolesse, Chem. Commun., 2011, 47, 4255 DOI: 10.1039/C0CC05491G

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