Issue 10, 2012
From the journal:

Chemical Communications

Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion†‡

Robert S. P. Turbervilla  and  Jose M. Goicoechea*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK
E-mail: jose.goicoechea@chem.ox.ac.uk
Fax: +44 1865 272690
Tel: +44 1865 275961

Abstract

Reaction of the hydrogenheptaphosphide dianion, [HP7]2−, with one equivalent of bis(2,6-diisopropylphenyl)carbodiimide yielded the exo-functionalized cluster [P7C(NDipp)(NHDipp)]2− (Dipp = 2,6-diisopropylphenyl). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.

Graphical abstract: Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion

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DOI
https://doi.org/10.1039/C1CC12089A
Article type
Communication
Submitted
12 Apr 2011
Accepted
06 Jun 2011
First published
16 Jun 2011

Chem. Commun., 2012,48, 1470-1472

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Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion

R. S. P. Turbervill and J. M. Goicoechea, Chem. Commun., 2012, 48, 1470 DOI: 10.1039/C1CC12089A

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