Issue 10, 2012
From the journal:

Chemical Communications

Synthesis and reactivity of a uranyl-imidazolyl complex†‡

Michael F. Schettini,a   Guang Wua  and  Trevor W. Hayton*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, USA
E-mail: hayton@chem.ucsb.edu
Tel: 805-893-3392

Abstract

Treatment of [UO2(Ar2nacnac)Cl]2 with 4 equiv. of Li(C4H5N2) results in the formation of a rare uranyl organometallic complex [Li(MeIm)][UO(μ-O)(Ar2nacnac)(μ-C,N-C4H5N2)2] (2), in moderate yield. Reaction of 2 with 1 equiv. of MCl2 (M = Fe, Co) yields the bimetallic complexes [MCl(MeIm)][UO2(Ar2nacnac)(μ-N,C-C4H5N2)2] (M = Fe, 3; M = Co, 4).

Graphical abstract: Synthesis and reactivity of a uranyl-imidazolyl complex

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Article information

DOI
https://doi.org/10.1039/C1CC13192C
Article type
Communication
Submitted
30 May 2011
Accepted
26 Jul 2011
First published
22 Aug 2011

Chem. Commun., 2012,48, 1484-1486

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Synthesis and reactivity of a uranyl-imidazolyl complex

M. F. Schettini, G. Wu and T. W. Hayton, Chem. Commun., 2012, 48, 1484 DOI: 10.1039/C1CC13192C

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