Issue 10, 2012
From the journal:

Chemical Communications

Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides†‡

Scott A. Sulway,a   Richard A. Layfield,*a   Floriana Tuna,a   Wolfgang Wernsdorferb  and  Richard E. P. Winpenny*ac  

* Corresponding authors

a School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: Richard.Layfield@manchester.ac.uk

b Institut Néel, CNRS and Université J. Fourier, BP 166, 25, Avenue des Martyrs, Grenoble, France

c The Photon Science Institute, The University of Manchester, Oxford Road, Manchester, UK
E-mail: Richard.Winpenny@manchester.ac.uk

Abstract

[Cp2Dy(thf)(μ-Cl)]2 (2) was synthesized from [Cp2Dy(μ-Cl)]n, which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased.

Graphical abstract: Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

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Article information

DOI
https://doi.org/10.1039/C1CC14643B
Article type
Communication
Submitted
28 Jul 2011
Accepted
27 Aug 2011
First published
16 Sep 2011

Chem. Commun., 2012,48, 1508-1510

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Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

S. A. Sulway, R. A. Layfield, F. Tuna, W. Wernsdorfer and R. E. P. Winpenny, Chem. Commun., 2012, 48, 1508 DOI: 10.1039/C1CC14643B

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