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Abstract | Cited by

Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes.

Graphical abstract: Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

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