Issue 13, 2012

NHC-catalyzed thioesterification of aldehydes by external redox activation

Abstract

The NHC-catalyzed thioesterification of aromatic or aliphatic aldehydes with a range of thiols was developed in the presence of a stoichiometric amount of an organic oxidant. Among the oxidants examined, phenazine was shown to give the best results in terms of chemical yield and compatibility with thiols.

Graphical abstract: NHC-catalyzed thioesterification of aldehydes by external redox activation

Supplementary files

Article information

Article type
Communication
Submitted
18 Nov 2011
Accepted
16 Dec 2011
First published
06 Jan 2012

Chem. Commun., 2012,48, 1901-1903

NHC-catalyzed thioesterification of aldehydes by external redox activation

T. Uno, T. Inokuma and Y. Takemoto, Chem. Commun., 2012, 48, 1901 DOI: 10.1039/C2CC17183J

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