Issue 43, 2012
From the journal:

Chemical Communications

Ionic galleries: a bilayered host–guest cocrystal of C-propyl pyrogallol[4]arene with an ionic liquid†‡§

Drew A. Fowler,a   Simon J. Teat,b   Gary A. Baker*a  and  Jerry L. Atwood*a  

* Corresponding authors

a Department of Chemistry, University of Missouri-Columbia, Columbia, USA
E-mail: bakergar@missouri.edu, atwoodj@missouri.edu

b Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS 6R2100, Berkeley, USA

Abstract

We report on a cocrystal between C-propyl pyrogallol[4]arene and the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate exhibiting a remarkable bilayer topology comprising two unique host–guest complexes resulting from the ionic liquid cation binding in two distinctive orientations relative to the macrocycle.

Graphical abstract: Ionic galleries: a bilayered host–guest cocrystal of C-propyl pyrogallol[4]arene with an ionic liquid

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Article information

DOI
https://doi.org/10.1039/C2CC31510F
Article type
Communication
Submitted
29 Feb 2012
Accepted
29 Mar 2012
First published
30 Mar 2012

Chem. Commun., 2012,48, 5262-5264

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Ionic galleries: a bilayered host–guest cocrystal of C-propyl pyrogallol[4]arene with an ionic liquid

D. A. Fowler, S. J. Teat, G. A. Baker and J. L. Atwood, Chem. Commun., 2012, 48, 5262 DOI: 10.1039/C2CC31510F

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