Issue 75, 2012
From the journal:

Chemical Communications

Chiral assembly of dodecahedral cavities into porous metal–organic frameworks†

Hui Yang,ab   Fei Wang,a   Yao Kang,a   Tie-Hu Lib  and  Jian Zhang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: zhj@fjirsm.ac.cn
Fax: +86-591-83715030
Tel: +86-591-83715030

b School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, P. R. China

Abstract

Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M2(CO2)4] units and trimeric [M3(μ3-OH)(CO2)6] units leads to two isomorphous chiral microporous metal–organic frameworks, where the heterometallic framework has high surface area and excellent CO2/N2 adsorption selectivity.

Graphical abstract: Chiral assembly of dodecahedral cavities into porous metal–organic frameworks

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC35024F
Article type
Communication
Submitted
20 May 2012
Accepted
01 Aug 2012
First published
03 Aug 2012

Chem. Commun., 2012,48, 9424-9426

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Chiral assembly of dodecahedral cavities into porous metal–organic frameworks

H. Yang, F. Wang, Y. Kang, T. Li and J. Zhang, Chem. Commun., 2012, 48, 9424 DOI: 10.1039/C2CC35024F

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