Issue 90, 2012
From the journal:

Chemical Communications

Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes†

Georg Bender,a   Gerald Kehr,a   Constantin G. Daniliuc,‡a   Quang Minh Dao,§b   Stephan Ehrlich,§b   Stefan Grimme§b  and  Gerhard Erker*a  

* Corresponding authors

a Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster, Germany
E-mail: erker@uni-muenster.de

b Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie der Universität Bonn, Beringstrasse 4, 53115 Bonn, Germany

Abstract

The five-membered zirconacycloallenoids 2 react rapidly with dihydrogen under mild conditions to yield the corresponding (s-cis-conjugated diene)zirconocenes 3. The reaction involves splitting of the H2 molecule between the metal center and a ligand carbon atom.

Graphical abstract: Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes

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Article information

DOI
https://doi.org/10.1039/C2CC36189B
Article type
Communication
Submitted
25 Aug 2012
Accepted
19 Sep 2012
First published
21 Sep 2012

Chem. Commun., 2012,48, 11085-11087

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Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes

G. Bender, G. Kehr, C. G. Daniliuc, Q. M. Dao, S. Ehrlich, S. Grimme and G. Erker, Chem. Commun., 2012, 48, 11085 DOI: 10.1039/C2CC36189B

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