Multicomponent self-sorting of a Pd7 molecular boat and its use in catalytic Knoevenagel condensation

Dipak Samanta; Partha Sarathi Mukherjee

doi:10.1039/C2CC37377G

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Multicomponent self-sorting of a Pd₇ molecular boat and its use in catalytic Knoevenagel condensation†‡

Dipak Samanta^a and Partha Sarathi Mukherjee*^a

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^a Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India
E-mail: psm@ipc.iisc.ernet.in
Fax: +91-80-2360-1552
Tel: +91-80-2293-3352

Abstract

Unique three-component self-assembly of a cis-blocked 90° Pd(II) acceptor with a mixture of tri- and tetra-imidazole donors led to the self-sorting of a Pd₇ molecular boat with an internal nanocavity, which catalyses the Knoevenagel condensation of a series of aromatic aldehydes with 1,3-dimethylbarbituric acid and Meldrum's acid in aqueous media.

This article is part of the themed collection: Emerging Investigators 2013

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Article information

DOI: https://doi.org/10.1039/C2CC37377G
Article type: Communication
Submitted: 09 Oct 2012
Accepted: 17 Dec 2012
First published: 18 Dec 2012

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Chem. Commun., 2013,49, 4307-4309

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Multicomponent self-sorting of a Pd₇ molecular boat and its use in catalytic Knoevenagel condensation

D. Samanta and P. S. Mukherjee, Chem. Commun., 2013, 49, 4307 DOI: 10.1039/C2CC37377G

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