Issue 60, 2013
From the journal:

Chemical Communications

Low-energy regeneration and high productivity in a lanthanide–hexacarboxylate framework for high-pressure CO2–CH4–H2 separation†

Yabing He,*a   Hiroyasu Furukawa,b   Chuande Wu,c   Michael O'Keeffe,d   Rajamani Krishna*e  and  Banglin Chen*f  

* Corresponding authors

a College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China
E-mail: heyabing@gmail.com

b Department of Chemistry, University of California, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

c Department of Chemistry, Zhejiang University, Hangzhou 310027, China

d Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287, USA

e Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands
E-mail: r.krishna@nva.nl

f Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
E-mail: banglin.chen@utsa.edu
Fax: +1-210-458-7428

Abstract

A porous lanthanide–organic framework UTSA-62a of a jjt-a topology has been synthesized from a hexacarboxylate and structurally characterized, exhibiting significant potential for use in CO2–CH4–H2 separation (H2 purification) processes with high productivities and low regeneration costs when operating at high pressure and room temperature.

Graphical abstract: Low-energy regeneration and high productivity in a lanthanide–hexacarboxylate framework for high-pressure CO2–CH4–H2 separation

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Article information

DOI
https://doi.org/10.1039/C3CC43196G
Article type
Communication
Submitted
30 Apr 2013
Accepted
06 Jun 2013
First published
07 Jun 2013

Chem. Commun., 2013,49, 6773-6775

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Low-energy regeneration and high productivity in a lanthanide–hexacarboxylate framework for high-pressure CO2–CH4–H2 separation

Y. He, H. Furukawa, C. Wu, M. O'Keeffe, R. Krishna and B. Chen, Chem. Commun., 2013, 49, 6773 DOI: 10.1039/C3CC43196G

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