Issue 18, 2013
From the journal:

Journal of Materials Chemistry A

Transmetalation: routes to metal exchange within metal–organic frameworks†

Marianne Lalonde,‡a   Wojciech Bury,‡ab   Olga Karagiaridi,a   Zachary Brown,a   Joseph T. Hupp*a  and  Omar K. Farha*a  

* Corresponding authors

a Department of Chemistry, Northwestern University, Evanston, Illinois, USA
E-mail: o-farha@northwestern.edu

b Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, Warsaw, Poland

Abstract

The present work is a critical review of metal exchange (transmetalation) involving metal nodes and metalated struts in metal–organic frameworks. Particular emphasis is given to drawing parallels between different examples of transmetalation in order to understand the influence of coordination environment, solvents, nature of the metals and other variables on the process. We hope that the present review will be of use to those involved in the incorporation of various metal centers to create isostructural MOFs and study their properties.

Graphical abstract: Transmetalation: routes to metal exchange within metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C3TA10784A
Article type
Feature Article
Submitted
23 Feb 2013
Accepted
20 Mar 2013
First published
21 Mar 2013

J. Mater. Chem. A, 2013,1, 5453-5468

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Transmetalation: routes to metal exchange within metal–organic frameworks

M. Lalonde, W. Bury, O. Karagiaridi, Z. Brown, J. T. Hupp and O. K. Farha, J. Mater. Chem. A, 2013, 1, 5453 DOI: 10.1039/C3TA10784A

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