Issue 69, 2014
From the journal:

Chemical Communications

Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity†

Wen Zhou,a   Brian O. Patrickb  and  Kevin M. Smith*a  

* Corresponding authors

a Department of Chemistry, University of British Columbia Okanagan, 3333 University Way, Kelowna, BC, Canada
E-mail: kevin.m.smith@ubc.ca
Tel: +1 250 807 9933

b Department of Chemistry, University of British Columbia, Vancouver, BC, Canada

Abstract

Paramagnetic CpCr[(RN)2C6H4] compounds (R = SiMe3, CH2CMe3 and Ph) were treated with R′N3 azides to generate chromium imido complexes, CpCr[(RN)2C6H4](NR′), with R′ = adamantyl, aryl or SO2Ar. The H-atom abstraction reactivity of the imido complexes differed as the R and R′ substituents were varied.

Graphical abstract: Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity

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Article information

DOI
https://doi.org/10.1039/C4CC04545A
Article type
Communication
Submitted
15 Jun 2014
Accepted
14 Jul 2014
First published
14 Jul 2014

Chem. Commun., 2014,50, 9958-9960

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Influence of redox non-innocent phenylenediamido ligands on chromium imido hydrogen-atom abstraction reactivity

W. Zhou, B. O. Patrick and K. M. Smith, Chem. Commun., 2014, 50, 9958 DOI: 10.1039/C4CC04545A

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